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Journal: Journal of Mass Spectrometry
Article Title: Phthalates and Mixed Alkyl Phthalates Analysis in Plastics Using GC‐MS With Cold EI
doi: 10.1002/jms.70062
Figure Lengend Snippet: Extracted ion mass chromatograms of a diisodecyl phthalate (DIDP) standard acquired at m/z = 432.3, 446.3, and 460.3 (top to bottom) using GC‐MS with Cold EI. The data demonstrates how Cold EI can uniquely detect the presence of mixed alkyl phthalates (iso‐nonyl‐decyl phthalate and Iso‐decyl‐undecyl phthalate) within the DIDP standard and provide their relative concentration as shown on the Y axis.
Article Snippet: Then, the ChromatoProbe was placed into the GC inlet for thermal desorption for 0.6 min.
Techniques: Gas Chromatography-Mass Spectrometry, Concentration Assay
Journal: Journal of Mass Spectrometry
Article Title: Phthalates and Mixed Alkyl Phthalates Analysis in Plastics Using GC‐MS With Cold EI
doi: 10.1002/jms.70062
Figure Lengend Snippet: GC‐MS with Cold EI analysis of a small piece (below 1 mm 3 ) of a black electricity cable using ChromatoProbe for sample introduction and thermal desorption. The total ion mass chromatogram is shown on top with the names of the phthalates identified marked with an arrow. At the bottom, the mass spectrum of the last eluting peak, which is a heavy phthalate ( m / z = 546.4), is presented, along with its identification parameters from the NIST EI mass spectral library and corresponding structural formula.
Article Snippet: Then, the ChromatoProbe was placed into the GC inlet for thermal desorption for 0.6 min.
Techniques: Gas Chromatography-Mass Spectrometry, Thermal Desorption
Journal: Journal of Mass Spectrometry
Article Title: Phthalates and Mixed Alkyl Phthalates Analysis in Plastics Using GC‐MS With Cold EI
doi: 10.1002/jms.70062
Figure Lengend Snippet: GC‐MS with Cold EI analysis of a small piece (below 1 mm 3 ) of a twist tie using ChromatoProbe for sample introduction and thermal desorption. The total ion mass chromatogram is shown on the top with the names of several phthalates identified marked with an arrow. The mass spectrum of the marked peak, which is a mixed alkyl phthalate, is shown at the bottom, including the compound's identification parameters from the NIST EI mass spectral library.
Article Snippet: Then, the ChromatoProbe was placed into the GC inlet for thermal desorption for 0.6 min.
Techniques: Gas Chromatography-Mass Spectrometry, Thermal Desorption
Journal: Journal of Mass Spectrometry
Article Title: Phthalates and Mixed Alkyl Phthalates Analysis in Plastics Using GC‐MS With Cold EI
doi: 10.1002/jms.70062
Figure Lengend Snippet: GC‐MS with Cold EI analysis of a small piece (< 1 mm 3 ) of a brown electricity cable using ChromatoProbe for sample introduction and thermal desorption. The total ion mass chromatogram is shown on the top. The extracted ion mass chromatograms for m / z = 404.3, 418.3432.3, 446.3, and 446.3 — corresponding to various phthalates and mixed alkyls — are shown at the bottom, highlighting the peak within the red box. As shown in the figure, the extended range of GC‐MS with Cold EI and its enhanced molecular ions enables the detection and identification of the different phthalates inside a mixture.
Article Snippet: Then, the ChromatoProbe was placed into the GC inlet for thermal desorption for 0.6 min.
Techniques: Gas Chromatography-Mass Spectrometry, Thermal Desorption